A Highly Flexible Dinuclear Ruthenium(II)-Platinum(II) Complex: Crystal Structure and Binding to 9-Ethylguanine

A highly flexible dinuclear ruthenium(II)-platinum(II) complex: crystal structure and binding to 9-ethylguanine.

Crystal Structure of Human Soluble Adenylate Cyclase Reveals a Distinct, Highly Flexible Allosteric Bicarbonate Binding Pocket

Soluble adenylate cyclases catalyse the synthesis of the second messenger cAMP through the cyclisation of ATP and are the only known enzymes to be directly activated by bicarbonate. Here, we report the first crystal structure of the human enzyme that reveals a pseudosymmetrical arrangement of two catalytic domains to produce a single competent active site and a novel discrete bicarbonate bindin...

A dinuclear cadmium(II) Schiff base thiocyanato complex: crystal structure and fluorescence.

A new dinuclear cadmium(II) complex, [Cd(L)(NCS)]2 (1) has been synthesized using a potentially tetradentate Schiff base ligand HL, 2-((E)-(2-(diethylamino)ethylimino)methyl)-6-methoxyphenol, obtained by the condensation of 2-diethylaminoethylamine and o-vanillin, and characterized by different physicochemical techniques. Crystal structure of the title complex was unambiguously established by s...

Synthesis and Crystal Structure of Cs3nb2br9, a Dinuclear Niobium Cluster

SYNTHESIS AND CRYSTAL STRUCTURE OF CS3NB2BR9, A DINUCLEAR NIOBIUM CLUSTER. The niobium bromide cluster compound, Cs3Nb2Br9, was obtained by solid-state synthesis techniques in reaction of stoichiometric amounts of CsBr, Nb powder and NbBr5. It crystallizes in the hexagonal system with unit cell parameters a = 7.7183(2) Å, c = 18.3396(7) Å, space group P63/mmc, Z = 2. Its crystal structure was d...

Synthesis, crystal structure, DNA binding and cleavage activities of oximato bridged cationic dinuclear copper(II) complex having labile ligands

Oximato bridged dinuclear copper(II) complex [Cu(L)(CH3OH)]2(ClO4)2 with an oxime-Schiff base ligand, viz. 3-[2-[(dimethylamino)ethyl]imino]-2-butanoneoxime (HL), has been synthesized and structurally characterized. The dinuclear copper(II) complex crystallizes in monoclinic space group P21/n with the unit cell parameters, a = 13.3564(9) Å, b = 12.0821(8) Å, c = 17.5045(11) Å, β = 90.097, V = 2...